The Evolving Appalachian NGL Storage Hub and Petrochemical Industry
Hub
The Appalachian Basin is now home to one under construction
ethane cracker in Beaver County, Pennsylvania along the Ohio River and possibly
one or two more ethane crackers downstream, one possibly in Belmont County,
Ohio. Plans for underground ethane storage and possibly underground
undifferentiated NGL storage (propane and butanes) are also in the works.
Currently NGLs are also being piped across Pennsylvania and to other points
south and west for export or to petrochemical complexes along the Gulf Coast or
Ontario, Canada. Most shale gas plays are rich in NGLs (natural gas liquids,
including ethane, propane, butanes, and natural gasoline) and the Appalachian
plays including the Utica, Marcellus, and Upper Devonian Geneseo/Burket shales
are especially NGL-rich in fairly well-defined fairway trends on the
southwestern part of the plays, based on geochemical maturity. Those trends
overlap quite a bit and thus the NGLs of these reservoirs occupy a fairly
concentrated geographical area. This makes it an ideal area for an NGL
feedstock-based petrochemical hub.
Comparison of the future Appalachian NGL hub to the
petrochemical complexes in Louisiana is probably not a good one since the Louisiana
area processes crude oil as well as NGLs. Although both products act as
petrochemical feedstocks to some of the same end-products, many more products
can be derived from crude oil as well as significantly more pollutants like
sulfur compounds being expected from refining and processing crude oil than in
processing NGLs.
Business people are excited about the potential for jobs and
subsidiary and ancillary industries developing to support the ethane
cracker(s). Oil & gas operators are excited at the potential of more local
ethane demand and ethane prices high enough to make a profit from separating it
from the natural gas stream. Midstream operators like it because it will mean
less ethane and other NGLs in the natural gas they send to customers which must
meet pipeline quality standards that require a cap on NGLs to keep in their BTU
range. Several local plastics processors are developing expansion plans.
Geological Suitability for Appalachian NGL Storage
An oil and natural gas research consortium associated with
West Virginia University and state Geologic Surveys did a year-long study of
the geologic suitability for ethane/NGL underground storage and found several
potential reservoirs at different stratigraphic and structural depths across a
large area from north of the main producing areas to south of the main
producing areas. Several reservoirs show suitable porosity, permeability,
trapping, and sealing conditions required for storage. These area(s) will need
to be connected to producing areas via pipelines. Some areas have stacked storage
reservoir potential. Others are within or very similar to natural gas storage
fields. My guess is that those reservoirs closest to the producing areas will
be prioritized for storage since this would require less additional pipeline
infrastructure. Consortium lead author WVU’s Douglas G. Patchen noted: “The
study revealed that we have adequate storage potential for NGLs in three types
of storage "containers: “solution cavities in the Salina F4 salt, mined
cavities in the Greenbrier Limestone, and depleted gas reservoirs in older
producing fields and gas storage fields.” Another lead author, WVU’s Brian J.
Anderson added: “The challenge, however, is to develop a transportation and
storage infrastructure that is sufficient enough to retain some of the NGLs in
this area to support a revitalized petrochemical industry.”
One proposed ethane storage facility in salt caverns in
Monroe County, Ohio has seen significant delay due to the Ohio Dept. of Natural
Resources (ODNR) being slow to approve it. Apparently, they are concerned about
the integrity of storage in the Salina salt caverns, which would presumably be
made cavernous by water injection to bring the salt into solution with water,
then the ethane/NGLs (they also plan to store some propane and butanes) would
also be pumped in to dissolve in the water and then separated back out when the
NGLs are retrieved. Construction of the
nearly $500 million project has been delayed until mid-2018. Initial costs will
be about $150 million. The project was first announced in early 2016. In April
2016 they drilled and completed a test well. This determined that the thickness
of the proposed salt layer was adequate. For pumping out the stored ethane
and/or NGLs, construction of a 3.25 million-barrel brine pond would be
required. Perhaps that and the fact that such facilities are new to the region
is part of the reason for the ODNR delay. Another facility, I believe has been
proposed for Marshall County, WV.
On Nov. 9, 2017 when President Trump was visiting China it
was announced that China signed a Memorandum of Understanding that they would
invest “$83.7 billion in the State of West Virginia–largely in shale and
shale-related petrochemical projects.” This is projected to occur over a
20-year period.
The availability of natural gas liquids as feedstocks can
support ethylene-derived plastics. Ethane crackers make ethylene which is
transported as a liquid to facilities that convert it to polyethylene pellets
which are then used as feedstock for various polyethylene (PET) plastics. NGLs
are also feedstocks for alkylates (from butanes) for gasoline additives,
butadiene (from butanes) for rubber, LP gas (from propane and butanes), propylene
(from propane) for polypropylene plastics, and heavy NGLs (ie. pentanes,
hexanes, natural gasoline) are used as gasoline additives, special purpose
solvents, and to dilute tar sands oil bitumen to help it flow through
pipelines. There are many other uses for the separated NGLs including as
refrigerants, aerosol propellants, and as fuels for lighters, stoves, furnaces,
forklifts, lawn equipment, and motor vehicles.
The Appalachian petrochemical and NGL storage hub will also
require pipelines to transport liquids such as ethylene between plants as well
as pipelines from storage fields to plants. Before that there is a need for
pipelines from natural gas wells to processing and fractionation plants and
from there to the proposed storage fields. Pipelines that transport NGLs need
to be able to withstand and operate within certain temperatures and pressures
which makes them more expensive to build and with most pipelines being delayed
these days due to organized public opposition there is predicted to be a significant
short-term shortage of NGL supplies, particularly ethane, to the growing
facilities along the Gulf Coast while at the same time Gulf Coast natural gas
and NGL production slows, even after a few NGL pipelines were built to ship
NGLs from Appalachia to the Gulf Coast. It makes better economic (and
environmental) sense to feed plants nearby rather than far away.
In Appalachia a greater percentage of the natural gas stream
along the wet gas and NGL fairways has access to processing and fractionation
plants that separate the NGLs into various components and pipeline them to
production facilities – since more fractionation has been added over the last
few years. Before the fractionation plants separate the NGL stream into
individual NGL components such as ethane, propane, etc., impurities like
sulfur, CO2, and helium are removed in processing facilities. Thus, natural gas
processing plants involve several chemical steps. NGLs are typically separated
cryogenically by temperature.
Projections suggest that lower-priced ethane-derived
polyethylene will thrive in the U.S. with costs competing with those in the
Middle East which currently has the lowest cost for ethylene. This will
eventually result in a surplus that can increase exports from the U.S. of
polyethylene pellets and finished plastics. The cheaper polyethylene feedstocks
should help European plastics manufacturers since they have been struggling
with profitability. Some now receive exports of ethane and other NGLs via
specially-designed tanker ships. The chance for better profitability is why
European, Asian, Latin American, and companies from all over the world are
investing in U.S. NGL-derived petrochemical companies as well as building their
own facilities in the U.S. The Bain and Co. 2013 report referenced below notes
that: “Future investments are likely to flow toward North America, not only for
petrochemicals but also for industries further downstream.” Thus far they have
been correct. According to Kinder Morgan: “The American Fuel &
Petrochemical Manufacturers association estimates that feedstocks account for
60 to 70 percent of the total cost to manufacture petrochemicals.” Thus, the
U.S. now has a quite substantial cost advantage for these feedstocks and is set
to dominate the petrochemical industry and subsidiary manufacturing industries,
although the Middle East still has cost advantage in some sections. The American
Chemistry Council “reports that as of March 2017, 294 chemical manufacturing
projects cumulatively valued at $179 billion in capital investment had been
proposed, were under construction, or were recently completed in the United
States as a result of the shale gas boom.” Kinder Morgan notes that about 60%
of those expansions are being built by foreign companies. The American Chemistry
Council estimates that chemical and plastics investment in Appalachian
facilities could eventually reach $36 billion and create 100,000 jobs. The
Appalachia Development Group which heads the Appalachia Storage and Trading Hub
Initiative recently was approved for the early phases of what is estimated to
be a $1.9 billion loan from the U.S. DOE.
Although there is some uncertainty in predicting future
profit margins for ethane, ethylene, and other NGLs and NGL products, the
overall outlook looks good for the U.S. Some analysts think there will be a
bubble as demand rises and supply falls, partly due to the rising amounts of
exports. Facilities along the Gulf Coast may have some lack of supply issues as
new ethane crackers began coming online there in 2017. Ethane prices may rise
faster than expected 2017-2019 as the glut of Appalachian supply is constrained
by lack of takeaway capacity. As local Appalachian cracker(s) come online in
2020 and beyond and ethane and NGL storage fields are built the local demand
will rise, keeping upward pressure on prices. However, with new pipelines, some
pipeline storage, and more ethane recovered rather than rejected the
Appalachian supply should continue to grow substantially. Until then, ethane
will continue to be rejected into the natural gas stream. Other analysts think
there won’t be a bubble because of long-term formula pricing for some firms and
because there may be more pipeline storage capacity than stated by midstream
companies since keeping this storage capacity private gives them advantages in
negotiating price agreements – which would be another form of what I call
‘capacity manipulation.’ While it may seem devious I believe it is perfectly
legal. However, it is also inefficient as it does not make full use of what is
available at any given time.
Methanol and Fertilizer Plants Via Methane Feedstock
Methane, the main component of natural gas, can be used as a
feedstock for methanol plants and fertilizer plants. The produced methanol can then
be used as a feedstock for chemicals, antifreeze, gasoline, and gas-to-liquids
(GTL) applications. Plans for two but possibly up to five methanol plants have
been announced in West Virginia with construction on the first one beginning in
Sept. 2017. Both are in Kanawha County near Charleston where there is a long
established chemical industry. In both cases much of the plants are being
shipped from other areas of the world (Brazil, Slovenia) to take advantage of
the much cheaper Appalachian natural gas feedstock prices. Several large
fertilizer plants came on line in 2016 and 2017, mostly along the Gulf Coast. I
don’t believe any fertilizer plants have been announced in the Appalachian
region but as the nation’s premier source area for natural gas that is certainly
a possibility.
Natural gas can also be seen as an energy feedstock for
manufacturing facilities that require a lot of energy. Everything from latex
paint plants to ammonia plants to cement plants to basic manufacturing
facilities can benefit from the lower fuel and electricity prices from natural
gas abundance.
Environmental Implications of Petrochemical Hubs
The Ohio Valley Environmental Coalition likens the evolving
storage and petrochemical hub to a horror story but of course there is NGL
storage and associated petrochemical plants in several other places in the U.S.
and Canada. While there may be some health issues with people living very close
to oil refineries and petrochemical facilities this is not expected to be an
issue here by regulators and most citizens. Of course, siting of facilities
will be a factor as well. Storage fields likely won’t be developed in populated
areas and presumably the petrochem facilities won’t either. However, locations
along the Ohio River are likely due to the potential of shipping products by
barge and other factors. While ethane steam crackers and other petrochemical
and chemical industries do make pollution and CO2 emissions, newer modern
facilities should make less of both, especially as feedstock being close to
processing areas leads to less emissions due to transportation.
Much has been said about the dense petrochemical industry
along the Gulf Coast of Louisiana where many different kinds of plants take
advantage of their close proximity to better their economics. However, such
concentration can also be potentially risky for very local residents as each
facility emits both greenhouse gases, adds to local combustion pollutants, flared
byproducts, and adds significantly to emissions of quite a few volatile organic
compounds (VOCs). VOCs contribute significantly to ground level ozone, or
photochemical smog, which is implicated in asthma and respiratory disorders
like COPD. Others have argued that cancer rates along what has become known as
“Cancer Alley” are high. While this is debatable, people are not likely to want
to live very close to these facilities. This is probably going to be a factor
with Appalachian facilities. Whether smog develops has a lot to do with local
weather patterns as well. Air emissions can also fall to the ground and affect
soil and groundwater concentrations of various contaminants. Leaks and spills
can happen. Of course, all these facilities submit emissions plans to state
regulatory agencies which then approve them after they are satisfied with them.
According to the Yale 360 article referenced below: “Researchers
have found benzene in the air, ethylene dichloride in groundwater, and high
dioxin levels in the blood of residents of “Cancer Alley.” These are all
chemicals that are known or probable carcinogens, and toxic to health in other
ways as well.” Some say the concentration of industries also concentrates
contaminants and effects are cumulative. Toxicologists note that the “the dose
makes the poison,” that some chemicals accumulate while others don’t, and that
determining any specific causes or contributors to cancer is difficult. South
African company Sasol has built a large ethane cracker along the Gulf Coast and
soon the world’s first commercial “ethylene tetramerization unit” which makes
plastic-strengthening chemicals out of ethylene. They bought out about half the
residents living close to the facility but the other half chose to stay and
will have to deal with any contaminants coming from this new commercial
chemical process. Environmental justice advocates will likely be watching very
closely as they will with any new Appalachian facilities.
References:
Appalachian Storage Hub: A Petrochem Horror – by Ohio Valley
Environmental Coalition (Blog), Jan. 4, 2018
A Geologic Study to Determine the Potential to Create an Appalachian
Storage Hub for Natural Gas Liquids – multiple authors, edited by Kristen M.
Carter and Douglas G. Patchen, Appalachian Oil and Natural Gas Research
Consortium, West Virginia University, July 31, 2017
US Methanol Breaks Ground on First Plant in West Virginia – in
Marcellus Drilling News, Sept. 7, 2017
How Petrochemical Companies Can Thrive in the NGL Boom – by Jason
McLinn, Mark Porter, and Tom Shannon, in Bain and Co. (Brief), Nov. 21, 2013
Natural Gas Liquids to Olefins – (power point presentation) –
University of Wyoming
The Role of Natural Gas Liquids (NGLs) in the American Petrochemical
Boom – Kinder Morgan White Paper, June, 2017
Can’t Get There From Here: Prospects for Ethane Production and
Transportation from the Marcellus/Utica – by Kelly Van Hull, in RBN Energy,
Oct. 18, 2017
Commentary: U.S. Ethane Uncertainty – by Will Beacham, in ICIS Chemical
Business (News) Feb. 24, 2017
Natural Gas Boom Brings Major Growth for U.S. Chemical Plants – by
Rachel Cernansky, in Yale 360, Jan. 29, 2015
Webinar will discuss Research on Underground Natural Gas Liquids
Storage – webinar by Penn State Extension's Marcellus Education Team, Jan. 18,
2018
Ohio Continues to Drag Feet Approving Mountaineer NGL Storage – in
Marcellus Drilling News, Jan 17, 2018
More Clarity on Status of Mountaineer NGL Storage Facility in OH – in Marcellus
Drilling News, June 17, 2017
Mountaineer NGL Says 20 Drillers Interested in Ethane Storage – in
Marcellus Drilling News, Oct. 17, 2017
Mountaineer NGL Storage Spending Up to $500M on Ethane Facility – in
Marcellus Drilling News, Oct. 27, 2017
China Agrees to Invest Amazing $83.7 BILLION in WV Shale, Petchem – in
Marcellus Drilling News, Nov. 9. 2017
More on that Massive $83.7B Chinese Investment in WV Shale/Petchem – in
Marcellus Drilling News, Nov. 10, 2017
Natural Gas Briefing Document #1 – Natural Gas Liquids – by Brookings
Energy Security Initiative, Natural Gas Task Force, Brookings Institute, 2012
Potential Appalachia Storage and Trading Hub Clears Hurdle – by Sara
Welch, in Shale Gas Reporter, Jan. 10, 2018