Thursday, August 27, 2015

The Current Local Controversy Over Waste Water Injection Wells in Southeastern Ohio and the Unlikelihood of Further Induced Seismicity in the State

The Current Local Controversy Over Waste Water Injection Wells in Southeastern Ohio and the Unlikelihood of Further Induced Seismicity in the State
 
This is an issue of local concern to me as I live near a town that has voted unanimously to ban fracking and some of whose constituents are advocating tirelessly to ban waste water injection wells in the county. As a geologist I have some knowledge of these issues. I have stayed out of these local debates, preferring to leave them to the official spokespeople of the industry such as the ODNR, the Ohio Oil and Gas Association (OOGA), Energy-In-Depth (EID), and others.


Having gotten a letter from my local water company about the dangers of injection wells I was aghast at the misunderstandings. Apparently, this group ACFAN (Athens County Fracking Action Network) is advising them quite erroneously about why there are waste water disposal wells in Ohio rather than other states (ie. Pennsylvania). They are advising that this is due to Ohio having less stringent requirements for permitting such wells. This is simply untrue. There are two basic reasons that Ohio is far preferable than PA: 1) Many of the reservoir rocks at depth in Ohio are significantly underpressured relative to pressure gradient compared to the rocks at depth in PA. This allows them to accept more water. Pressure gradient is also higher in PA, ie. rocks at 4000 ft depth in southeastern Ohio might have a pore fluid pressure of less than 800 psi while rocks at the same depth in PA might have a pore fluid pressure of 3000 psi. This is due to greater compaction due to burial at greater burial depths in the basin-center regions of PA and WV relative to the basin-marginal areas of Ohio. Thus, reservoir rocks in PA are typically at higher pressure at depth (higher pressure gradient or psi/ft below surface) and so it is generally easier to inject fluids into the Ohio rocks. Pennsylvania also has more overpressured reservoirs, where the reservoir pressure is actually higher than the pressure gradient. This means that Ohio rocks tend to accept more fluids than PA rocks. 2) Ohio has more brine-bearing reservoirs at depth (deep saline aquifers) than PA. Some are significantly naturally fractured which helps them accept more water. A few a naturally underpressured and some are pressure-depleted. Under-pressured or pressure depleted brine-bearing reservoirs or under-pressured reservoirs that are significantly naturally fractured are ideal for water disposal because they will accept water easily at lower injection pressures - with rising pressure being temporary, dropping as the water moves away from the well bore via injection pressures. ODNR was given primacy by the Federal EPA to regulate waste water injection wells because its rules equal or exceed those of the EPA regarding these class II injection wells. This is the case for several states. The state (Ohio) does tend to approve permits significantly faster (than EPA-regulated PA) due to pro-business efficiency and more staff devoted to the task. 


There may be some potential for waste water injection in Pennsylvania in pressure depleted Oriskany Sandstone gas fields. These wells have lower pressure, being depleted of their reservoir fluids. Pressure depleted reservoirs are thought to have very good long term capacity but injectivity is dependent on permeability of the rock. At least one proposed and initially approved injection well permit was later rejected by the EPA (who controls underground injection in PA) likely due to public concerns. Perhaps the most pertinent issue there is that both the well operator and the EPA failed to identify many of the fresh water wells within a quarter mile, which is required. It is uncertain why this is the case and how well documented water wells are in the state. Certainly it was a serious oversight. The wells being permitted there should be approved and likely will be at some point as there should be no reason to be concerned about fresh water aquifers. There is also some possibility for depleted Clinton/Medina wells in northwest PA to be converted to injection wells. 

Early in the development of Pennsylvania Marcellus wells the frac flowback and produced waters were treated in public waste water treatment plants. Most of these plants were not equipped to remove some of the contaminants. Before the rule was in effect the PADEP asked producers to avoid certain of the most ill-equipped plants and they complied quite readily. This practice was halted in 2011 and it probably should have not been permitted in the first place. Water with high concentrations of total dissolved solids (TDS), bromides, barium, and some with unacceptable levels of radioactivity due to radium isotopes has been found near discharge areas.  However, these are no longer problems and surface water quality in southwest PA has improved.

Radioactivity in Shales and Brines

The source of radioactivity in flowback and produced Marcellus waters was originally thought to be from dissolved radioactive shale fines from the drilling and fracking processes but studies have indicated that the radioactivity is present in existing formation brines. Some wells likely also tap into Oriskany brines which likely have similar compositions. The Oriskany Sandstone is one of the injection zones in Southeastern Ohio and Athens County and adjacent areas where fluids are contained in updip stratigraphic pinchouts. Since radioactivity is already present in these formation brines then injecting more radioactive brines should not be problematic. See references. Recently, an industry colleague has confirmed to me that Oriskany brine waters from PA are typically "hot," or radioactive. The high capacity and deeper Clinton/Medina sandstones and Newburg/Lockport dolomite as well as the shallower fractured Devonian shales are also injection zones in this area. The Oriskany, Onondaga, and Devonian shales are considered to have less capacity and be low volume injection zones while the Silurian Newburg/Lockport and Clinton/Medina are high volume injection zones. I am not aware of any radioactivity in the Silurian brines but since they are not adjacent to an organic-rich black shale I would suspect much lower naturally occurring radioactivity.    



Injection Well Construction

Another serious error I have noted with the endless coverage of anti-injection well groups is that they appear to be misinformed about how wells are constructed to protect fresh water aquifers. There are typically three strings of high pressure rated steel casing cemented in place. Cement bond surveys and other detection surveys are run to make sure the cement is fully functional as a fluid barrier. Sometimes it falls out a bit at the bottom or where it washes out so that it does not come to the top but in those cases it is typically back filled then re-checked with surveys and casing pressures are always monitored. Lastly, a steel production casing is run inside the other casing strings to the injection depth. This does not need to be cemented in place to the total depth as the other strings protect fresh water zones. A packer is inserted around the injection casing to prevent any fluid from coming up around the injection casing and the pressure is monitored. In addition there are typically thousands of feet of rock between the injection zone and fresh water aquifers including aquicludes, which are impermeable layers of very fine-grained rocks like non-organic shale. Typically, there is one just above the reservoir into which the water is injected which acts as a seal for the reservoir fluids. There are many many studies that show that fluid boundaries such as these are rarely compromised and even if one was there would still be thousands of feet of rock including more impermeable layers to seal fluids in, especially at the low rock pressures in southeastern Ohio. The ODNR and other regulators assign maximum allowable surface pressures. The EPA has recently praised the ODNR underground injection control (UIC) program as more than adequate and responsive to problems.

http://www.ohio.com/blogs/drilling/ohio-utica-shale-1.291290/u-s-epa-hails-ohio-s-injection-well-program-for-drilling-wastewater-1.625017 


Underground Reservoir Fluids and Characteristics

Incidentally, also in those rocks underground there are fluids like natural gas, condensate, crude oil, in some cases hydrogen sulfide, and other sulfur compounds, sometimes CO2, nitrogen, possibly even helium in some places. There are also organic Devonian shales rich in uranium, thorium, radium, etc., and so radioactive. Some of these naturally-occurring gases and substances are inert but most have some level of toxicity- most are more poisonous than the dilute hydro-fracking waste water that is injected. It should also be remembered that groundwater and formation fluids move laterally very slowly. While groundwater movement is dependent on recharge and discharge dynamics and can move quickly, fluids at depth are much more strongly confined and flow is limited and typically on the scale of inches per year. It may move further and faster at higher injection pressures. The Battelle/RPSEA study noted that injection pressures drive fluid migration. They note that fluid injected into the injection wells is generally confined to an area around 3000 ft from the wellbore - and this is presumably in wells that have been injected into for 20 years or more in some cases. This migration can be detected by nearby wells drilled into the same formation. Fluid migration is certainly an issue in Oklahoma and Kansas allowing fluids to access basement faults that induce seismicity. This slow water movement is in great contrast to surface water which flows according to gradients provided by topography and gravity. Water injected at high volumes and pressures into deep saline aquifers does diffuse more quickly (possibly in the range of a half-mile per week as the Youngstown study indicates) but is confined to porous and permeable stratigraphic intervals according to the mechanisms of deep basinal fluid migration and the porosity and permeablility of the reservoir.

It also has been shown that so-called "make-up water," the frac water that goes into a well is different than what comes out. The water that comes out has more salts, heavy metals, and organics (benzene, etc.) than the make-up water. Since drilling mud is circulated out and reused, it is unlikely that any significant amounts of these components come from drilling mud. These higher concentrations of chemicals of concern are inherent in the naturally-occurring formation water. What this means is that the focus on fracking chemicals as dangerous relative to naturally occurring brine water is unwarranted. 

Brine water and Spills  


Typical Ohio brine waters from conventional wells are variable in chloride components but some are very salty (much saltier than seawater - up to 10 times) and the state reports that approximately 2% of oilfield brine is being poured on roads to melt snow in winter. This can cause accumulations of salt in groundwater as has apparently been documented. These brines are far from drinkable and are dangerous to plant life. I would say they would probably be more dangerous in drinking water than hydro-fracking make-up water mainly because it is far less dilute in general and more saline. Use of road salt has declined somewhat over the years in favor of other substances like calcium chloride, magnesium chloride, and organic agricultural by-products but rock salt (NaCl) and oilfield brine are still used considerably. It should be noted that surface spills would be magnitudes more likely to get into groundwater than any deep fluid injection. There is usually access from surface to aquifer and rarely if ever access from deep zones to aquifer.

Deliberate spills, or dumping of brine waters has occurred and this is, of course, a felony criminal offence, as it should be. There was one well-known case in Ohio where frac waste water was dumped into storm drains leading directly into a river. In North Dakota there have been several cases of deceptive injection well owners, one who moved a packer up the hole in order to be able to inject more fluid. This indicates that a compliance culture needs to be encouraged, developed, and enforced among oil & gas producer and injection well operators. 

Since waste water has been transported much more via pipeline rather than being trucked there have been far less spills, however, the spills (pipeline ruptures) that have occurred have been larger. This shows a need to be able to both anticipate spills before they occur and to detect them faster when they do occur. The trend is that legal liability for leak detection is being transferred to the "operators" of the water pipelines rather than the companies who utilize them (which may be multiple companies). 

Recent spills in Ohio and West Virginia have spurred lawmakers to propose new regulations regarding underground tanks and vaults that temporarily store wastewater and to require dyes so that spills can be found sooner. These have a fair liklihood to be enacted as these spills were preventable. One underground storage facility leaked, perhaps for a long time into a neighbor's pond and killed a significant amount of wildlife. Companies operating these wells need to ensure maximum protection against surface and shallow subsurface spills. 



Shallower Injection Via Enhanced Oil Recovery Projects

In southeastern Ohio there is some shallow oil in a formation known as the 2nd Berea. For many decades now there are places where this zone - at about 1100 to 1800 ft (it shallows westward) - has been water flooded which means that water is injected in to push oil out. Water comes out with the oil then is filtered and treated then re-injected. There are about 120,000 such projects in the U.S. There are no known instances of freshwater contamination through water flooding here of which I am aware. Certainly the most dangerous potential situation involving the local southeastern Ohio injection wells would be via a major spill, say if a holding tank or a truck leaked its contents. If not mitigated quickly it is possible such a spill could eventually rich a fresh water aquifer, especially a very shallow one. However, the injection well sites are properly diked with multiple containment that exceeds the contents of their holding tanks, so the chances of a spill getting into groundwater are very small.
 

Local Water Issues

The local water wells here in Meigs County tend to be deep - soft water which probably contains small amounts of chlorides and maybe sometimes a bit of methane as there is some shallow gas. Iron bacteria is fairly common and is typically mitigated with chlorine bleach. The local water company wants to be able to test for oil and gas "chemicals" that would be introduced into the aquifer thousands of feet above via injection well fluids but complains that they don't know what to test for since information on the chemicals used is unavailable. Of course there are many known chemicals and nearly all can be accessed through the Frac Focus database and through other means so that is not really a valid argument. Their overall concern is understandable due to the long term local contamination caused by the C8 (perfluorooctanoic acid) released directly into the surface environment by DuPont. However, there is a vast difference between releasing something directly into the surface environment and releasing it into the deep subsurface.      
 
The bottom line - the reason I write this post - is to counter the misunderstandings and hopefully to allay any fears people may have about the safety of their water. The biggest danger to my local water supply would likely come from the Ohio River where oil and gas leakage, if any, would make up just a small part of the total industrial leaks, pesticide and fertilizer runoff, iron bacteria, sewage leaks and raw sewage discharges, grey water, landfills, underground storage tanks, acid mine drainage, falling particulate matter etc., that affect the local watersheds and groundwater. Attempting to convince people that this one highly regulated potential source, which is carefully injected thousands of feet below aquifers, is more dangerous than the others is not realistic. When we still had the C8 in our local water I tended to avoid it but now that it is at virtually undetectable levels I don't. Two things I learned when studying water are 1) that it is most often a local issue, and 2) water can be cleaned (though the cost can get high to clean it at high levels). Of course, nobody wants contaminated water. There are tens of thousands of oil and gas wells in Ohio where the pipes come up through aquifers but there have been only a handful of cases of water contamination and in each case the cause was determined and remedied as needed: human error, spills, improper design or procedure, etc. Billions of barrels of oil and brine have come up through these pipes without any noticeable problems. The current oil and gas industry is much more conscious and less tolerant of improper procedure that could result in environmental problems than it has ever been in the past. It has to be. People who work in the industry want to produce their products safely and environmentally responsibly. 


Manageable Risk

While groups like ACFAN can show good organizational skills and documentation of spills and accidents, they fail to understand basic processes and so fail to convey an accurate picture of what is really happening or what is the actual level of risk. Someone could list thousands of cases of car accidents to point out the dangers of driving but we understand that it is an acceptable risk. Injecting brine and frac flow back water is also an acceptable risk. There are many other things the industry is doing to help: recycling as much water as possible, utilizing treated acid mine drainage for fracking to keep it out if the surface environment, researching new ways to treat and recycle waste water, and to dispose of effluents. Companies are also engaged in offsetting activities: restoring wilderness areas, wetlands, forests, and helping local communities, as well as providing jobs.


Water Treatment Facilities

Antero Resources and Veolia North America (the largest water treatment company in the world) just announced designing and building a state-of-the-art wastewater treatment complex initially able to process 60,000 barrels per day. Antero, along with many other companies, utilizes their own fresh water pipeline distribution system to move water to their wells to reduce trucking. Waste water treatment facilities can help companies recycle up to 100% of flow back and produced water. Other marketable byproducts can be produced such as salt and brine products for oilfield use. The treated water can be returned to the fresh water distribution system to be used on future wells. Such projects can potentially decrease the amount of waste water injection wells needed. There will likely be more of these projects in the future.


 
There are other new technologies for water treatment and recycling such as 'crystallization and evaporation' that are seen as alternatives to underground injection. Such processes involve large surface impoundments so the risk for spills is not really reduced and the advantages over deep well injection may not be great. Fairmont Brine Processing recently announced such a project capable of processing 52,500 Bbls per day. By-products that can be sold include sodium chloride and calcium chloride. They expect their project to be operational in 2018. 
  
Media, Activism, and Science


It would be best if the ACFAN people would cease and desist going around “educating” other people about these wells as they themselves are most certainly not properly educated about them. They have been very influential in the local area and their loud voice has been extremely well represented in local and regional media. In light of their incorrect knowledge, they should be challenged: by the ODNR, by the companies operating waste water injection wells, by the local oil & gas industry and their reps and PR groups (OOGA and EID) and by the EPA. Creating hysteria and sending out notices to tens of thousands of people that their water might be poisoned can be seen as a very serious accusation, one that had better be backed up by correct knowledge. That is not the case here.
 
Calls for monitoring wells near the tank batteries of injection wells have been deemed unnecessary by the ODNR and knowing the process and the geology this is quite understandable.  The ODNR could maybe provide other cases where water wells were monitored near injection wells. One should also understand that finding traces of chemicals in water similar to those used in oil and gas does not pinpoint the source of those chemicals, as well construction materials and other local sources of the same chemicals and chemical by-products can and do occur. This has been a problem with a few other monitoring efforts with the results often being misrepresented by media.



The ACFAN group has also complained repeatedly about the need to have public hearings before such wells are permitted but when ODNR had an informational format open-house they made a spectacle of it by loud protesting with signs and slogans. Many such hearings have been disrupted by anti-drilling groups which makes them uncomfortable to others. In any case ODNR is not required to have such hearings and has never had them in the past. These people have an agenda. A few years ago they put up a billboard with children and flowers and a smoking burning oil rig in the background. They are manipulative. Unfortunately, people are falling for their ability to portray themselves as knowledgeable experts which they are not, quite obviously to anyone who has some real knowledge. Groups like ACFAN have no interest in making extractive industry processes safer and more accountable. Their goal is to ban those processes and this is pretty clearly stated. Science to them only has value if it confirms their own biases and supports their agenda. There are other environmental groups who are more reasonable and willing to work with industry and regulatory bodies to influence policy and solve problems. They tend to be more influenced by science and thus should have more influence on public policy than groups less informed by science. 

The argument that Ohio is a "dumping ground" for Pennsylvania fracking waste is not so valid if one considers that about 2-4 million gallons of injected frac fluid per well remain in the formation in each PA Marcellus well. Thus the complaint that up to 600,000 gallons of waste water per day injected in Athens County is extravagant is not valid as it would be equivalent to about 73 fracked wells per year. There are counties in PA that have drilled far more than 73 wells per year, although they are of course spread out over 73 or more sources of fluid rather than a handful in the county as in the injection wells. That number may be too small as it has been noted that 70% or more of the frac water injected into a production well does not return to the surface. That would be close to 120,000 barrels (5 million gallons) per well. In that scenario there would be only 42 wells worth of waste fluid injected annually in the county.  

There are about 150,000 waste water injection wells in the U.S. Most of these are small-scale enhanced recovery operations but about 30,000 wells are brine and flowback waste water injection wells. There have been very few problems with these wells concerning contamination.  Ohio has 211 injection wells. West Virginia has 76. Kentucky has 30. Pennsylvania only has 7. Geology, reservoir capacity, pressure relative to gradient, and permeability are all factors in a rock's ability to accept water and accommodate injection pressure tolerances. The avg. injection well in Ohio injects 32,000 barrels per year (1.34 million gallons) at an avg. reservoir pressure of 543 psi. In Ohio the Newburg/Lockport and Clinton/Medina formations have the most available volume and high injectivity. They also have had the most waste water injected.

Injection-Induced Seismicity

A very small percentage of wells have been associated with seismic activity and this is concerning. These wells have been associated with known and suspected faulting as it is well-known that fluid injection can trigger small earthquakes. In Oklahoma the USGS has determined that water injection along with water removal (many wells in Oklahoma, both conventional and unconventional produce lots of water along with oil and gas) has contributed to the upsurge in earthquakes. Wells in Ohio that have triggered earthquakes have been shut down. New rules, better volume and pressure monitoring, and better seismicity monitoring have been put in place here and in other areas. The case in Youngstown, Ohio has been examined in detail and it has been noted that sources of the injection-induced seismicity can be located with a high degree of accuracy so the seismic monitoring networks are adequate. Holtkamp etal. note that the monitoring networks in place can "quickly and inexpensively diagnose cases of induced seismicity and identify responsible well sites and operational parameters before induced events reach potentially destructive magnitudes." The uniqueness of the Youngstown case is that the injection zone was a 700+ ft interval from the Cambrian Copper Ridge Dolomite "B" Zone through the basal (Mt. Simon) sandstone and 200 ft into Proterozoic Precambrian basement rock. The Proterozoic interval was where the seismic events and thus the fault slippage was located. Most injection wells in Northeast Ohio inject into Silurian Age Lockport Dolomite (Newburg). Study of the Youngstown events was able to determine that the seismic events were a function of pore fluid pressure diffusion leading to fault slip with the slip leading to further pore fluid pressure diffusion (a positive feedback mechanism) . They were also able to determine that increasing injection pressures and volumes led to further diffusion and slippage and increased the area of potential failure of the fault zone. They also determined the diffusion rates by noting times between injection pressure increases and seismic events that were pinpointed to within 50 ft of accuracy in any direction. Finally, they also determined that ceasing injections led to drastic decreases in seismic events. This data suggests that injection-induced seismicity can be determined quickly, pinpointed to specific wells, and the wells shut down, likely leading to no further problems. Even though there have been quite a few individual cases of induced seismicity the phenomenon overall is still very rare and the increased cases are likely the result of the increased volumes of waste water being injected due to high-volume hydraulic fracturing of horizontal shale wells. As reservoir pressure decreases when fluids come out of the ground it increases when fluids are injected. That is a big part of the situation in Oklahoma - as pore fluid pressure diffuses further from the injection source due to higher reservoir pressure causing the fluids to move towards lower pressure there is more likelihood of accessing faults. The Cambro-Ordovician Arbuckle formation (roughly equivalent to the Knox and Copper Ridge formations of Ohio) which sits directly on top of basement rock is the main injection reservoir there with known access to basement faults. Researchers there (including the recent Stanford study) have noticed increased reservoir pressures in some places in the Arbuckle which moves the fluid that eventually intersects a fault which can cause fault slippage. The model developed by geophysicist Mark Zoback and colleagues at Stanford explains the time delay between injection and the small earthquakes as the time it takes for the pore pressure to diffuse and eventually intersect the basement fault. Oklahoma now injects 20 times the waste water that they did in 1997. Over 90% of the water is produced water rather than frac flowback water, so much of it is from conventional rather than unconventional development. Some Cambrian injection reservoirs in Ohio, Oklahoma, and Kansas are likely in hydraulic communication with Precambrian basement faults. Their situation in Oklahoma and Kansas is more dire than Ohio because their main injection reservoir sits directly on basement rock while in Ohio there are several shallower Paleozoic reservoirs: Clinton, Lockport, Oriskany, Huron Shale, etc. that are preferred to the Cambrian reservoirs. These shallower reservoirs are very unlikely to contact any basement faults. The Stanford authors conclude that stopping injection in the Arbuckle and instead injected into the Mississippi Lime where much of the produced water comes from is the best overall solution as it can be used for enhanced oil recovery. They do note that the pressure is still spreading in the Arbuckle and further intersections with basement faults and thus earthquakes are possible even after injection stops. In Ohio this is not an issue because most of the injection has been in shallower reservoirs far from basement rock. Recent actions in Oklahoma to shut-down certain injection wells and reduce pressures and volumes in others have resulted in a decrease in earthquakes, as expected in the modeling. The bottom line is that if the now obvious steps are taken injection-induced seismicity is not likely to be problematic in the future. The science-based approach is working. While the hydraulic fracturing process itself does generate detectable microseismic events, larger events are quite rare, far rarer than injection-induced seismic events. However, they do and have occured in a few places such as the U.K, Western Canada, and few other places. In Western Canada they occur associated with fracking the Montney and Duvernay shales. Apparently, the largest induced-seismicity event on record in the world at 4.5 on the Richter scale occurred in British Columbia in this context. Seismicity monitoring requirements and regulations for states and provinces have been or are being developed in areas where earthquakes occur. There are companies that can do detailed and accurate seismicity monitoring. Earthquakes and ground movement are also occasionally associated with gas or oil production in unconsolidated sandstones that can compact when depressurized. This was the case with an oil field near Long Beach, California where sinking land from subsurface compaction was the problem. It also occurs in the Groningen gas field in the Netherlands, owned by Shell and Exxon. Small earthquakes have been occurring for about 25 years near Groningen, often damaging nearby houses. The land surface there is soft clay which is more amenable to transmitting ground movement through the frequent small quakes. Whether earthquakes are "felt" is dependent on land surface - unconsolidated soils and rocks tend to transmit energy better which results in more perceived movement.

Potential for Lightning-Induced Fires and Explosions at Injection Well Facilities

Apparently, fires and explosions due to lightning have occurred at injection well facilities. The explosion/fire risk is due to volatile gases released during separation of oil and water. This is more common in areas that produce light volatile oil, such as North Dakota, Colorado, and Texas. Since 2013, North Dakota has had 3 events, Texas 4, and Colorado 2. Fiberglass tanks, although much longer lived than steel tanks since they resist corrosion due to the brine, are more prone to ignition by lightning. Risk can be minimized by reverting back to steel tanks, grounding, and ionizing. There is some expense to these processes and some have called for regulations requiring preventative action though none are yet in place. This has not happened in the eastern areas, perhaps due to the overall less volatile brine. It may well be related to the areas with light volatile oil, such as the Bakken, where train derailments have caused massive and catastrophic explosions.  
     
Future Waste Water Injection


Projections are that the need for brine and flowback waste water injection wells is expected to grow modestly over the coming years due to the increasing pre-eminence of high-volume hydraulic fracturing of horizontal wells, predominantly in shale gas and oil wells. This is not expected to overwhelm any capacity of available reservoirs for fluid disposal. This is despite the fact that currently in the Marcellus region about 87% of frack flowback water is recycled while about 13% is injected into disposal wells. It is thought to have improved to over 90% in 2014. The recycling rate in the Marcellus areas is the highest in the nation. With more water treatment facilities the amount of water recycled is likely to increase further. Several companies currently recycle 100% of their frac water and the trend is for more to do the same. This may cut the modest growth in injection predicted.One current prediction is for 5-10 new wells per year with some capable of receiving over 1 million barrels per year (avg. 3000-5000 barrels per day). Injection well owner-operators project that an injection well needs to be capable of injecting 1000 barrels per day in order to be economic. The best injection reservoirs in Ohio are probably the Newburgh/Lockport and the Clinton/Medina. While the Cambrian reservoirs may be able to take on large amounts of water the risk for seismic activity should be considered too risky and they should probably be avoided. That could even become an issue if Cambrian deep saline formations like the Mount Simon Sandstone become CO2 sequestration reservoirs, although the buoyant properties of CO2 may alter that possibility somewhat.

Latest News Update - Sept 2015

At the end of August a coalition of national, regional, and local environmentalist groups threatened to sue the EPA if it did not review and revise rules on oil & wastes as it apparently stated it would back in 1988. The issues of concern include injection wells, open air pits for temporary storage of frac flowback water, disposal of drill cuttings and solids in landfills that are not adequately lined, and spreading of frac waste brine on roads to melt snow. Induced seismicity is one of the biggest concerns with injection wells and I think with proper siting, monitoring, and injection zones that will not be a further problem in Ohio. If further events do occur then they would have to look at reducing injection pressures and volumes. The problem with drill cuttings and solid wastes includes heavy metals, some organics, and especially radioactivity although most studies suggests the radioactivity is low level and should not be problematic. As mentioned above there are plenty of alternatives to spreading oil and gas field brine on roads. My guess is that EPA may address some of these issues with small changes. Regarding injection wells they could possibly move to limit per well pressures and volumes as a safeguard against induced-seismicity. However, in light of recent understanding of the issues they may not. States are probably adequate to reduce risks.

It was recently announced in Athens County that baseline water testing will take place within a two-mile radius of injection wells paid for by Ohio University (as part of an on-going study that already did some baseline testing) and Athens County as the commissioners reported. It would be illogical to assume they will find anything at all related to oil and gas waste as I suspect they expect to find, but since it is baseline testing it assumes that further testing will occur in the future presumably at further cost to the university and the county - update Dec. 2015 - the first battery of tests showed zero contamination. A trace of naturally-occurring methane was all that was detected. Second battery of tests scheduled for March 2016.    
 

The ODNR has a video on their website that shows the whole injection well construction and functioning process.


http://oilandgas.ohiodnr.gov/industry/underground-injection-
 


References:

Geochemical Evaluation of Flowback Brine from Marcellus Gas Wells in Pennsylvania, USA - by Lara O. Haluszczak, Arthur W. Rose, and Lee R. Kump, in Applied Geochemistry 
2012

Shale Energy Produced Fluids Management and UIC Disposal Trends - by Dave Yoxtheimer, PG, Hydrologist, Penn State Marcellus Center for Outreach and Research, presentation for GWPC Annual UIC Conference, Austin, TX February 10, 2015.

Regional Detection and Monitoring of Injection-Induced Seismicity: Application to the 2010-2012 Youngstown, Ohio Seismic Sequence - by S.G. Holtkamp, M.R. Brudzinski, and B.S. Curie in AAPG Bulletin Vol. 99, No. 9 (Sept. 2015) pp.1671-1688

Oklahoma Earthquakes Linked to Oil and Gas Wastewater Disposal Wells, say Stanford Researchers in Stanford Report - June 18, 2015 (news.stanford.edu)

Water and Shale Gas - by Paul Ziemkiewicz (West Virginia University) - presented at 2nd Environmental Considerations in Energy Production Conference, Sept. 2015

North Dakota Saltwater Disposal Enforcement Highlights Key Legal Risks - posted in Oil Pro - Sept. 30, 2015

Potential Injection-Induced Seismicity Associated With Oil & Gas Development: A Primer on Technical and Regulatory Considerations Informing Risk Management and Mitigation - Report by States First, Ground Water Protection Council, and Interstate Oil and Gas Compact Commission 2015  

Injection Wells: An Introduction to Their Use, Operation, and Regulation - Groundwater Protection Council - Sept. 2013 

Subsurface Brine Disposal Framework in the Northern Appalachian Basin: Injection Horizons, Geology, and Operational Data - by Battelle, National Energy Technology Lab (NETL), Research Partnership to Secure Energy for America (RPSEA), and WV, OH, PA, KY Geological Surveys - 2015

Development of Subsurface Brine Disposal Framework in the Northern Appalachian Basin - by Joel R. Sminchak and Dr. Neeraj Gupta, Batelle - presented at RPSEA Onshore Technology Workshop, Oct 27, 2015

Challenges and Strategies for Monitoring Induced Seismicity - presented by Dario Baturan of Nanometrics at Ohio Geological Society meeting, October 29, 2015 

Shell and Exxon's 5 billion Euro problem: gas drilling that sets off earthquakes and wrecks homes, news story - by Lucas Amin, in The Guardian, Oct. 10, 2015

Energy Pipeline: Exposure to Lightning Strikes at Injection Well Facilities - by Gary Beers in Energy Pipeline (Covering the Energy Industry in Colorado), August 9, 2015 

Incorporating Induced Seismicity in the 2014 United States National Seismic Hazard Model -Results of 2014 Workshop and Sensitivity Studies - by Mark D. Peterson, Charles S. Mueller, Morgan S. Moschetti, Susan M. Hoover, Justin L. Rubenstein, Andrea L. Llenos, Andrew J. Michael, Williuam J. Ellsworth, Arthur F. McGarr, Austin A. Holland, and John G. Anderson, USGS Open-File Report 2015-1070, 2015

Injection Wells and Earthquakes: Quantifying the Risk - A Report by Energy In Depth, Nov. 2015

Evaporation and Crystallization as an Alternative to Deep Well Injection - by Brian Kalt, posted in LinkedIn Pulse, Dec 10, 2015

Abstract 08: Class II Injection in the Wenlockian-Ludlowian Lockport Dolomite, Northeastern Ohio - by Michael P. Solis, in Eastern Unconventional Oil & Gas Symposium, Lexington, Kentucky, Nov. 5-7, 2014

Vienna Oil Spill Leaves Slew of Dead Animals - by Amanda Smith, in WKBN News, Youngstown, April 3, 2015

Ohio Representatives Want More Rules for Injection Wells - by Gerry Ricciutti, in WKBN News, Youngstown, Jan. 12, 2016 

 












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